Total synthesis of naturally occurring Oxylipin has been achieved from open chain gluco-configured building block which is readily assembled from inexpensive and commercially available D-(+)-gluconolactone. Grignard reaction and Wittig olefination reactions are key steps for the requisite C–C bond formation. © 2017

Indrapal Singh Aidhen

Department Of Chemistry

Santosh Ramdas Borkar

Carbohydrates

Chains

Stereoselectivity

Synthesis (chemical)

BARTON-MCCOMBIE DEOXYGENATION

Bond formation

Building blockes

Grignard reaction

Naturally occurring

Stereo-selective

Total synthesis

Wittig olefination

Chemical reactions

carbon

gluconolactone

natural product

oxylipin

unclassified drug

XYLO( 8,9,10 TRIHYDROXY) 6 OCTADECENOIC ACID

BETA-GLUCONO-1,5-LACTONE

GLUCONIC ACID

lactone

article

covalent bond

drug synthesis

Olefination

priority journal

Wittig reaction

chemistry

Stereoisomerism

synthesis

Chemistry Techniques, Synthetic

GLUCONATES

Lactones

OXYLIPINS

IIT Madras is a public technical and research university located in Chennai, Tamil Nadu. Founded in 1959, it is recognised as an Institute of National Importance.

IIT Madras has been ranked as the top engineering institute in India for four years in a row by the National Institutional Ranking Framework of the MHRD

It currently offers undergraduate, postgraduate and research degrees across 16 disciplines in Engineering, Sciences, Humanities and Management. About 596 faculty belonging to science and engineering departments and centres of the Institute are engaged in teaching, research and industrial consultancy.

IIT Madras

Carbohydrate Research

A new and convenient synthesis of 2-O-benzyl-3, 4: 5, 6-di-O- isopropylidene-D-glucitol has been accomplished and has been generalized with the syntheses of differently protected D-glucitols at C-2 position. In the course of our new route to the differently protected D-glucitols at C-2 position, a new D-gluco configured building block, 1-morpholino-(3, 4: 5, 6-di-O-isopropylidene)-D-gluconamide has been achieved.

Journal of Carbohydrate Chemistry

2-O-benzylation in D-gluconamide derivative under basic conditions with complete retention of stereo-integrity: Convenient access to 2-O-benzyl-3,4:5,6-di-O-isopropylidene-D-glucitol and other differently protected D-glucitol derivatives

Synthesis and characterization of Ga-containing MAX phase thin films

Dental Abstracts

Ch-ch-ch-changes

New Biotechnology

Bioconverted products of essential fatty acids as potential antimicrobial agents

Journal of Natural Products

Oxylipins fromDracontium loretense

Stereoselective total synthesis of Oxylipin from open chain gluco-configured building block

Journal	Data powered by TypesetCarbohydrate Research
Publisher	Data powered by TypesetElsevier Ltd
ISSN	00086215
Open Access	No