This study presents the characteristics of real world, real time, on-road vehicular exhaust emission namely, carbon monoxide (CO), nitric oxide (NO), hydrocarbons (HC), and carbon dioxide (CO2) emitted under heterogeneous traffic conditions. Field experiments were performed on major category of vehicles in developing countries, i.e. two-wheelers, auto-rickshaws, cars and buses. The on-board monitoring was carried out on different corridors with varying road geometry. Results revealed that the driving cycle was dependent on the road geometry, with two lane mixed flow corridor having lot of short term events compared to that of arterial road. Vehicular emissions during idling and cruising were generally low compared to emissions during acceleration. It was also found that emissions were significantly dependent on short term events such as rapid acceleration and braking during a trip. Also, the standard emission models like COPERT and CMEM under predicted the real world emissions by 30–200% depending upon different driving modes. The on-road emissions measurements were able to capture the emission characteristics during the micro events of real world driving scenarios which were not represented by standard vehicle emission measured at laboratory conditions. © 2017 Elsevier Ltd