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Magnetic properties of ZrNiAl-type R3Mn3SiGa 2 compounds (R = Y, Gd, Tb, Dy and Ho)
Published in
2010
Volume: 502
   
Issue: 2
Pages: 261 - 269
Abstract
Magnetic properties of R3Mn3SiGa2 (R = Y, Gd, Tb, Dy, Ho) compounds (hexagonal ZrNiAl-type structure; space group P6̄2m, No.189) have been studied. Powder neutron diffraction results on Tb3Mn3SiGa2, Dy3Mn 3SiGa2 and Ho3Mn3SiGa2 compounds are presented. Magnetization data on Gd3Mn 3SiGa2 sample reveal a transition at about 155 K (T N) and an anomaly at 44 K whereas the compounds with R = Tb, Dy, Ho and Y order magnetically at 125 K, 55 K, 60 K and 163 K respectively, in 0.5 T applied field. Magnetization has linear field dependence at 5 K for all these compounds. Neutron data in zero applied field reveal three magnetic transitions for Tb3Mn3SiGa2 compound: at Tm1ND∼180K, Tm2ND=90K and Tm3ND=40K respectively, whereas the Ho3Mn 3SiGa2 compound shows magnetic transitions at Tm1ND∼165K, Tm2ND∼80K and Tm3ND=40K. Neutron diffraction study reveals that the magnetic structure is antiferromagnetic cone with wave vectors K 1 = [1/3, 1/3, 0], K2 = [1/2, 1/2, 0] for both the compounds. The magnetic structure of Dy3Mn3SiGa 2 is also an antiferromagnetic cone but with wave vector K 2 = [1/2, 1/2, 0]. The low temperature magnetic transition is attributed to a possible spin reorientation process. © 2009 Elsevier B.V.
About the journal
JournalJournal of Alloys and Compounds
ISSN09258388
Open AccessNo
Concepts (28)
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    Antiferromagnetics
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    Applied field
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    Field dependence
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    Low temperatures
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    Magnetic measurements
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    Magnetic transitions
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    Magnetization data
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    Neutron data
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    POWDER NEUTRON DIFFRACTION
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    Space groups
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    SPIN-REORIENTATION PROCESS
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    WAVE VECTOR
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    ZRNIAL-TYPE STRUCTURE
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    Antiferromagnetic materials
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    Antiferromagnetism
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    Dysprosium compounds
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    Gadolinium
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    Holmium
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    Magnetic devices
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    Magnetic properties
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    Magnetic structure
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    Magnetic variables measurement
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    Manganese
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    Neutron diffraction
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    Neutrons
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    Rare earths
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    Terbium alloys
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    Manganese compounds