Treatment of tri-O acetyl-D-galactal 1 and tri-O-acetyl-D-glucal 2 with diverse alcohols in the presence of LiBF4 in CH3CN, furnished alkyl, 2,3- unsaturated glycopyranosides 3-18 (50-86%).

Boga Sobhana Babu

Kalapattukuppuswamy Kuppuswamy B. Balasubramanian

GLYCOPYRANOSIDE

LITHIUM TETRAFLUOROBORATE

natural product

unclassified drug

ACETYLATION

article

catalysis

chemical binding

chemical reaction

reaction analysis

Spectroscopy

structure analysis

synthesis

IIT Madras is a public technical and research university located in Chennai, Tamil Nadu. Founded in 1959, it is recognised as an Institute of National Importance.

IIT Madras has been ranked as the top engineering institute in India for four years in a row by the National Institutional Ranking Framework of the MHRD

It currently offers undergraduate, postgraduate and research degrees across 16 disciplines in Engineering, Sciences, Humanities and Management. About 596 faculty belonging to science and engineering departments and centres of the Institute are engaged in teaching, research and industrial consultancy.

IIT Madras

Synthetic Communications

Lithium tetrafluoborate catalyzed ferrier rearrangement - Facile synthesis of alkyl 2,3-unsaturated glycopyranosides

Journal	Synthetic Communications
Publisher	Marcel Dekker Inc.
ISSN	00397911
Open Access	No