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Influence of organic matter and solute concentration on nitrate sorption in batch and diffusion-cell experiments
, , Neelancherry Remya, Rafig Azzam
Published in Elsevier B.V.
2011
PMID: 21232937
Volume: 102
   
Issue: 9
Pages: 5283 - 5289
Abstract
Nitrate sorption potentials of three surface soils (soils-1-3) were evaluated under different solute concentrations, i.e. 1-100mgL-1. Batch and diffusion-cell adsorption experiments were conducted to delineate the diffusion property and maximum specific nitrate adsorption capacity (MSNAC) of the soils. Ho's pseudo-second order model well fitted the batch adsorption kinetics data (R2>0.99). Subsequently, the MSNAC was estimated using Langmuir and Freundlich isotherms; however, the best-fit was obtained with Langmuir isotherm. Interestingly, the batch adsorption experiments over-estimated the MSNAC of the soils compared with the diffusion-cell tests. On the other hand, a proportionate increase in the MSNAC was observed with the increase in soil organic matter content (OM) under the batch and diffusion-cell tests. Therefore, increasing the soil OM by the application of natural compost could stop nitrate leaching from agricultural fields and also increase the fertility of soil. © 2010 Elsevier Ltd.
About the journal
JournalData powered by TypesetBioresource Technology
PublisherData powered by TypesetElsevier B.V.
ISSN09608524
Open AccessNo
Concepts (47)
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    Adsorption capacities
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    Agricultural fields
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    Batch adsorption
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    BATCH ADSORPTION EXPERIMENTS
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    CELL ADSORPTION
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    CELL TEST
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    Diffusion properties
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    LANGMUIR AND FREUNDLICH ISOTHERMS
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    Langmuir isotherm
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    NITRATE LEACHING
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    Organic matter
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    PSEUDO-SECOND ORDER MODEL
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    SOIL ORGANIC MATTER CONTENTS
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    SOLUTE CONCENTRATIONS
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    SORPTION POTENTIAL
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    SURFACE SOIL
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    Adsorption
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    Biogeochemistry
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    Biological materials
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    Composting
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    Diffusion
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    Dyes
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    Experiments
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    Holmium
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    Isotherms
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    Leaching
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    Nitrates
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    Organic compounds
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    Soil testing
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    Soils
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    Soil pollution
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    Nitrate
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    COMPOST
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    Field
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    Isotherm
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    SOIL FERTILITY
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    SOIL ORGANIC MATTER
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    Solute
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    Agriculture
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    Article
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    Kinetics
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    Priority journal
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    Soil analysis
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    Environmental remediation
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    Organic chemicals
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    Soil
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    Temperature