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Equilibrium and non-equilibrium cluster phases in colloids with competing interactions
Published in Royal Society of Chemistry
2014
Volume: 10
   
Issue: 25
Pages: 4479 - 4486
Abstract
The phase behavior of colloids that interact via competing interactions-short-range attraction and long-range repulsion-is studied by computer simulation. In particular, for a fixed strength and range of repulsion, the effect of the strength of an attractive interaction (ε) on the phase behavior is investigated at various colloid densities (ρ). A thermodynamically stable equilibrium colloidal cluster phase, consisting of compact crystalline clusters, is found below the fluid-solid coexistence line in the ε-ρ parameter space. The mean cluster size is found to linearly increase with the colloid density. At large ε and low densities, and at small ε and high densities, a non-equilibrium cluster phase, consisting of elongated Bernal spiral-like clusters, is observed. Although gelation can be induced either by increasing ε at constant density or vice versa, the gelation mechanism is different in either route. While in the ρ route gelation occurs via a glass transition of compact clusters, gelation in the ε route is characterized by percolation of elongated clusters. This study both provides the location of equilibrium and non-equilibrium cluster phases with respect to the fluid-solid coexistence, and reveals the dependencies of the gelation mechanism on the preparation route. © The Royal Society of Chemistry 2014.
About the journal
JournalData powered by TypesetSoft Matter
PublisherData powered by TypesetRoyal Society of Chemistry
ISSN1744683X
Open AccessYes
Concepts (13)
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    Computer simulation
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    Gelation
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    Glass transition
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    Solvents
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    Attractive interactions
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    COLLOIDAL CLUSTERS
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    COMPETING INTERACTIONS
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    CONSTANT DENSITY
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    FLUID-SOLID COEXISTENCE
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    GELATION MECHANISMS
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    MEAN CLUSTER SIZE
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    Thermodynamically stable
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    Colloids