Reduction of cyclohexanone to cyclohexanol using propane-2-ol as hydrogen donor has been carried out in vapor phase on CeXZr1-XO2 solid solutions synthesized by combustion at 302°C. The solid solutions around 0.4 mol% cerium content show better catalytic activity compared to pure ZrO2 and the selectivity to cyclohexanol is 98%. A moderate acid-base and good redox properties of CeXZr1-XO2 solid solutions are seen to be responsible for the catalytic activity. A possible mechanism of hydride transfer has been proposed with cerium ions as promoters.

Gangavarapu Ranga Rao

Department Of Chemistry

H. Ranjan Sahu

Catalyst activity

Catalyst selectivity

CERIUM COMPOUNDS

combustion

Phase composition

Reaction kinetics

Redox reactions

reduction

Solid solutions

Synthesis (chemical)

Cyclohexanol

Cyclohexanone

Hydride transfer

VAPOR PHASE REDUCTION

Ketones

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Vapor phase reduction of cyclohexanone to cyclohexanol on CexZr1-xO2 solid solutions

Reaction Kinetics and Catalysis Letters

CeO2-ZnO composite catalysts prepared by amorphous citrate method have been investigated for cyclohexanol dehydrogenation and hydrogen transfer reactions. The precursors and catalysts have been characterized by TGA, CHN analysis, XRD, UV-vis-NIR diffuse reflectance, SEM and acid-base measurements. The amorphous precursors in citrate process contain one molecule of citric acid per Ce4+ or Zn2+ ions. Structural studies of composite oxides indicate the presence of individual oxide phases along with non-equilibrium solid solutions in a limited composition range. The composite oxides contain low coordination Ce3+ and Ce4+ sites. Cyclohexanone was obtained as main product for cyclohexanol transformation reaction carried out over these mixed oxide catalysts due to dehydrogenation on basic sites. The presence of ceria in the composite oxide enhances the surface area and acid-base properties facilitating the dehydrogenation process. At low ceria content, the CeO2-ZnO composite oxide catalysts show higher catalytic activity for both cyclohexanol dehydrogenation and hydrogen transfer reactions due to higher basicity, surface area and smaller crystallite sizes. Hydrogen transfer activity is found to be higher on CeO2(10%)-ZnO catalyst prepared by citrate method compared to the catalyst prepared by decomposition from acetate precursor. This study demonstrates the promoting effect of ceria in CeO2-ZnO catalysts for reactions involving acid-base sites. © 2005 Elsevier B.V. All rights reserved.

Journal of Molecular Catalysis A: Chemical

Promoting effect of ceria on the physicochemical and catalytic properties of CeO2-ZnO composite oxide catalysts

Vapor phase reduction of cyclohexanone to cyclohexanol on CeXZr1-XO2 solid solutions

Journal	Reaction Kinetics and Catalysis Letters
ISSN	01331736
Open Access	No