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Synthesis and characterization of new vanadates of antimony, ASbV2O8 (A = K, Rb, Tl or Cs)Published in
1998
Issue: 18
Pages: 3013 - 3019
Four new vanadates of antimony, KSbV2O8 1, RbSbV2O8 2, TlSbV2O8 3 and CsSbV2O8 4, have been prepared by solid state synthesis and structurally characterized by single crystal X-ray diffraction. Compounds 1 to 3 have a three-dimensional (SbV2O8-)∞ anionic framework with one dimensional channels occupied by counter cations. Compound 4 has two dimensional (SbV2O8-)∞ layers interleaved with Cs+ ions. Both types of anionic frameworks are built from corner connected SbO6 octahedra and VO4 tetrahedra. The spectroscopic data are briefly discussed.
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About the journal
| Journal | Journal of the Chemical Society - Dalton Transactions |
|---|---|
| ISSN | 03009246 |
| Open Access | No |
Authors (1)
Kanamaluru Vidyasagar- Hydrothermal syntheses and characterization of phenyl- and benzyl-phosphonates and ethylene- and propylene-diphosphonates of cobalt(II), ACo(O3PR)2·xH2O and ACo(O3P-R-PO3)·2H2O (A = Ca, Sr, Ba; R = Ph, CH2Ph, -CH2CH2-, -CH2CH2CH2-)
- Syntheses and Characterization of 1,4-Phenylenebisphosphonates, A[HO3PC6H4PO3H2] (A = Li, K, Rb, Cs, Tl, Ag and NH4) and Crystal Structure of 1,4-Phenylenebisphosphonic Acid
- Syntheses, structure and rare earth metal photoluminescence of new and known isostructural A2Mo4Sb2O18 (A=Ce, Pr, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) compounds
- Syntheses and structural characterization of vanado-tellurites and vanadyl-selenites: SrVTeO5(OH), Cd2V2Te2O11, Ca3VSe4O13·H2O and Ba2VSe3O10
