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Synthesis and characterization of a two-coordinate manganese complex and its reaction with molecular hydrogen at room temperaturePublished in Wiley Online Library
2013
Volume: 52
Issue: 45
Pages: 11817 - 11821
The (cAAC)2Mn complex (cAAC=cyclic alkyl(amino)carbene) features a linear two-coordinate Mn-center. The antiferromagnetic coupling of a radical electron, delocalized on two carbene C-atoms, with the central MnI having d6 electronic configuration, mainly contributes to the S T=3/2 ground state. Treatment of (cAAC) 2Mn with H2 at RT resulted in the addition of H-atoms at both "carbene" C-atoms, leaving the central Mn-atom in the S T=5/2 spin ground state. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Postprint Version
Content may be subject to copyright.This is the peer reviewed version of the following article: [Synthesis and Characterization of a Two-Coordinate Manganes... ...This is the peer reviewed version of the following article: [Synthesis and Characterization of a Two-Coordinate Manganese Complex and its Reaction with Molecular Hydrogen at Room Temperature. Angewandte Chemie International Edition 52, 45 p11817-11821 (2013)], which has been published in final form at https://doi.org/10.1002/anie.201304642. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions: https://authorservices.wiley.com/author-resources/Journal-Authors/licensing/self-archiving.html#3.
About the journal
| Journal | Data powered by TypesetAngewandte Chemie - International Edition |
|---|---|
| Publisher | Data powered by TypesetWiley Online Library |
| ISSN | 14337851 |
| Open Access | No |
Authors (1)
Kartik Chandra Mondal- Two Structurally Characterized Conformational Isomers with Different C−P Bonds
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