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Structural refinement, optical and microwave dielectric properties of BaZrO 3
Published in
2012
Volume: 38
   
Issue: 3
Pages: 2129 - 2138
Abstract
In this work, barium zirconate (BaZrO 3) ceramics synthesized by solid state reaction method and sintered at 1670°C for 4 h were characterized by X-ray diffraction (XRD), Rietveld refinement, and Fourier transform infrared (FT-IR) spectroscopy. XRD patterns, Rietveld refinement data and FT-IR spectra which confirmed that BaZrO 3 ceramics have a perovskite-type cubic structure. Optical properties were investigated by ultraviolet-visible (UV-vis) absorption and photoluminescence (PL) measurements. UV-vis absorption spectra suggested an indirect allowed transition with the existence of intermediary energy levels within the band gap. Intense visible green PL emission was observed in BaZrO 3 ceramics upon excitation with a 350 nm wavelength. This behavior is due to a majority of deep defects within the band gap caused by symmetry breaking in octahedral [ZrO 6] clusters in the lattice. The microwave dielectric constant and quality factor were measured using the method proposed by Hakki-Coleman. The dielectric resonator antenna (DRA) was investigated experimentally and numerically using a monopole antenna through an infinite ground plane and Ansoft's high frequency structure simulator software, respectively. The required resonance frequency and bandwidth of DRA were investigated by adjusting the dimension of the same material. © 2011 Elsevier Ltd and Techna Group S.r.l.
About the journal
JournalCeramics International
ISSN02728842
Open AccessNo
Concepts (35)
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    Absorption and photoluminescence
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    CUBIC STRUCTURE
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    DEEP DEFECTS
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    Dielectric resonator antennas
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    Fourier transform infrared
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    Ft-ir spectrum
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    Functional applications
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    Ground planes
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    HIGH-FREQUENCY STRUCTURE SIMULATOR SOFTWARES
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    MICROWAVE DIELECTRIC CONSTANT
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    MICROWAVE DIELECTRIC PROPERTIES
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    Pl emission
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    Quality factors
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    Resonance frequencies
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    SOLID STATE REACTION METHOD
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    STRUCTURAL REFINEMENT
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    Symmetry-breaking
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    UV-VIS ABSORPTION SPECTRA
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    Xrd patterns
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    Antennas
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    Ceramic materials
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    Computer software
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    Defects
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    Dielectric devices
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    Energy gap
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    Microwave antennas
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    Optical properties
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    Perovskite
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    Rietveld refinement
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    Sintering
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    Solid state reactions
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    STRUCTURAL CERAMICS
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    Ultraviolet spectroscopy
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    X ray diffraction
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    BARIUM COMPOUNDS