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Ruthenium-catalyzed hydroarylation of anilides with alkynes: An efficient route to ortho -Alkenylated anilinesPublished in ACS Publications
2014
DOI: 10.1021/ol403666s
Volume: 16
Issue: 3
Pages: 912 - 915
Acetanilides reacted with symmetrical as well as unsymmetrical alkynes in the presence of [RuCl2(p-cymene)2], pivalic acid, and AgSbF6 in iso-PrOH providing ortho-alkenylated acetanilides in a highly regio- and stereoselective manner. Later, ortho-alkenylated acetanilides were converted into ortho-alkenylated anilines in the presence of HCl. © 2014 American Chemical Society.
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About the journal
| Journal | Organic Letters |
|---|---|
| Publisher | ACS Publications |
| ISSN | 15237060 |
| Open Access | No |
Authors (2)
Masilamani Jeganmohan- Alkylation, Annulation, and Alkenylation of Organic Molecules with Maleimides by Transition-Metal-Catalyzed C-H Bond Activation
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