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Rhodium catalyzed cyanation of chelation assisted C-H bonds
Published in
2013
PMID: 24041400
Volume: 15
   
Issue: 19
Pages: 4960 - 4963
Abstract
A rhodium-catalyzed cyanation of chelation assisted C-H bonds is described employing N-cyano-N-phenyl-p-methylbenzenesulfonamide as an efficient cyanating reagent. The present method allowed the synthesis of various benzonitirle derivatives in good to excellent yield. A number of chelating groups are also effective in the present cyanation of C-H bonds. In addition, the developed methodology was applied in the formal synthesis of the isoquinoline alkaloid, menisporphine. © 2013 American Chemical Society.
About the journal
JournalOrganic Letters
ISSN15237060
Open AccessNo
Concepts (14)
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    Chelating agent
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    Dyes, reagents, indicators, markers and buffers
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    Nitrile
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    Rhodium
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    Article
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    Catalysis
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    Chemical structure
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    Chemistry
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    Hydrogen bond
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    Chelating agents
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    Hydrogen bonding
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    Indicators and reagents
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    Molecular structure
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    Nitriles