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Reactivity of indole-3-alkoxides in the absence of acids: Rapid synthesis of homo-bisindolylmethanesPublished in Elsevier Ltd
2016
Volume: 72
Issue: 49
Pages: 8106 - 8116
An unprecedented behaviour of in situ generated indole-3-alkoxides (MgX or Li) has been reported. Tuning the electronic properties of the alkoxides offered the direct and selective construction of bisindolylmethanes and indole-3-carbinols. This process shows very broad scope and represents the reagent (external) free, greener synthesis of structurally divergent bisindolylmethanes. © 2016 Elsevier Ltd
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About the journal
| Journal | Data powered by TypesetTetrahedron |
|---|---|
| Publisher | Data powered by TypesetElsevier Ltd |
| ISSN | 00404020 |
| Open Access | No |
Authors (1)
Beeraiah Baire- Ag(I)-Catalyzed Cyclizative Hydration of Alkynes and Propargylic Alcohols. A Mild Approach to 2-Acylfuran Derivatives
- Intercepted Meyer–Schuster Rearrangements in Organic Synthesis
- Formal Halo-Meyer-Schuster Rearrangement of Propargylic Acetates through a Novel Intermediate and an Unexampled Mechanistic Pathway
- Mild Approach to 2-Acylfurans via Intercepted Meyer-Schuster Rearrangement of 6-Hydroxyhex-2-en-4-ynals
Concepts (43)
1 BENZYL 3 [1 (1 BENZYL 5 METHOXYINDOLIN 3 YL) 5 METHOXY 1H INDOLE- 1 BENZYL 3 [1 (1 BENZYL 5 METHOXYINDOLIN 3 YL)(THIOPHEN 2 YL)METHYL] 5 METHOXY 1H INDOLE
- 3 INDOLEMETHANOL
- 3,3' (3 CYCLOPROPYLPROP 2 YNE 1,1 DIYL)BIS(1 METHYL 1H INDOLE)
- 3,3' (3 PHENYLPROP 2 YN 1,1 DIYL)BIS(1 BENZYL 1H INDOLE)
- 3,3' (3 PHENYLPROP 2 YNE 1,1 DIYL)BIS(1 METHYL 1H INDOLE)
- 3,3' (4 METHYLPENT 2 YN 1,1 DIYL)BIS(1 METHYL 1H INDOLE)
- 3,3' (4 TOLYLMETHYLENE)BIS(1 METHYL 1H INDOLE)
- 3,3' (BUTANE 1,1 DIYL)BIS(1 METHYL 1H INDOLE)
- 3,3' (ETHANE 1,1 DIYL)BIS(1 METHYL 1H INDOLE)
- 3,3' (HEPT 2 YN 1,1 DIYL)BIS(1 METHYL 1H INDOLE)
- 3,3' (PHENYLMETHYLENE)BIS(1 METHYL 1H INDOLE)
- 3,3' (PROP 2 YNE 1,1 DIYL)BIS(1 HEXYL 1H INDOLE)
- 3,3' (PROP 2 YNE 1,1 DIYL)BIS(1 METHYL 1H INDOLE)
- 3,3' (PROPANE 1,1 DIYL)BIS(1 METHYL 1H INDOLE)
- 3,3' (THIOPHEN 2 YLMETHYLENE)BIS(1 BENZYL 1H INDOLE)
- 3,3' (THIOPHEN 2 YLMETHYLENE)BIS(1 METHYL 1H INDOLE)
- 3,3' (UNDEC 2 YN 1,1 DIYL)BIS(1 METHYL 1H INDOLE)
- 3,3' [(4 METHOXYPHENYL)METHYLENE]BIS(1 HEXYL 1H INDOLE)
- 3,3' [(4 METHOXYPHENYL)METHYLENE]BIS(1 METHYL 1H INDOLE)
- 3,3' [3 (3 CYCLOHEX 1 EN 1 YL)PROP 2 YN 1,1 DIYL]BIS(1 METHYL 1H INDOLE)
- 3,3' [3 (3 FLUOROPHENYL)PROP 2 YNE 1,1 DIYL]BIS(1 METHYL 1H INDOLE)
- 3,3' [3 (4 FLUOROPHENYL)PROP 2 YNE 1,1 DIYL]BIS(1 METHYL 1H INDOLE)
- 3,3' [3 (TRIMETHYLSILYL)PROP 2 YNE 1,1 DIYL]BIS(1 METHYL 1H INDOLE)
- 3,3' [3 [4 (TERT BUTYL)PHENYL]PROP 2 YN 1,1 DIYL]BIS(1 METHYL 1H INDOLE)
- Acid
- BISINDOLYLMETHANE DERIVATIVE
- INDOLE 3 ALKOXIDE DERIVATIVE
- Indole derivative
- Unclassified drug
- Unindexed drug
- Article
- Carbon nuclear magnetic resonance
- Column chromatography
- Crystal structure
- Drug structure
- Drug synthesis
- Green chemistry
- Mass spectrometry
- Priority journal
- Proton nuclear magnetic resonance
- Thin layer chromatography
- X ray diffraction
