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Production, characterization, and combustion of nanoaluminum in composite solid propellants
Jayaraman Kandasamy, Krishnasamy V. Anand, David S. Bhatt, ,
Published in American Institute of Aeronautics and Astronautics Inc.
2009
Volume: 25
   
Issue: 2
Pages: 471 - 481
Abstract
This paper reports the production of nanoaluminum particles using the wire explosion process at our laboratory. Electrical energy is applied to the aluminum wire in an argon atmosphere to yield spherical particles around 50 nm in size. The material is also characterized by a number of methods. The nano-Al is included in bimodal ammonium Perchlorate composite solid propellants, and their burning rates are compared with those containing normal micron- sized aluminum and nonaluminized propellants in a total of 21 formulations in the 1-12 MPa pressure range. Nanoaluminized propellants show ∼100% increase in burning rate relative to nonaluminized or microaluminized ones, but only when large-sized coarse ammonium Perchlorate particles are used. Burning-rate plateaus observed in non- and microaluminized propellants are washed out with the addition of nano-Al, but the burning rates of nanoaluminized propellants register low pressure exponents in the elevated pressure range. The results suggest that the heat feedback from the diffusion-limited combustion of nano-Al particles near the propellant burning surface controls the propellant burning rate when sufficiently large parts of the burning surface are made up of the nanoaluminized fine ammonium-perchlorate/binder matrix.
About the journal
JournalJournal of Propulsion and Power
PublisherAmerican Institute of Aeronautics and Astronautics Inc.
ISSN07484658
Open AccessNo
Concepts (31)
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    ALUMINUM WIRES
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    AMMONIUM PERCHLORATES
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    Argon atmospheres
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    Burning rate
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    Composite solid propellant
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    DIFFUSION LIMITED
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    Electrical energy
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    ELEVATED PRESSURE
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    HEAT FEEDBACK
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    Large parts
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    Low pressures
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    Matrix
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    NANO-AL
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    NANOALUMINUM
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    PRESSURE RANGES
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    PROPELLANT BURNING RATE
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    Spherical particle
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    Surface controls
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    WIRE EXPLOSION
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    Alumina
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    Aluminum
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    AMMONIUM COMPOUNDS
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    Argon
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    Explosives
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    Heat radiation
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    Solid propellants
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    Spacecraft propulsion
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    Surface diffusion
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    Thermochemistry
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    Wire
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    Combustion