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One step transformation of tricyclopentabenzene (trindane) [C15H18] to 4-[1R,2S,4R,5S)-1,2,5-trihydroxy-3-oxabicyclo[3.3.0]octane-4 spiro-1′-(2′-oxocyclopentan)-2-yl]butanoic acid [C15H22O7]
, , Bharadwaj Parimal, P. Madhusudanan K.
Published in Royal Society of Chemistry (RSC)
Issue: 20
Pages: 2239 - 2240

The complete, Ru(VIII) mediated oxidation of the benzene ring of trindane 1 is contained within the framework of peripheral methylenes to yield the unfragmented product 2.

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PublisherData powered by TypesetRoyal Society of Chemistry (RSC)
Open AccessNo