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Nanosecond laser treatment of a-Si thin films for enhanced light trapping and minority carrier lifetime in photovoltaic cells
Published in Japan Laser Processing Society
2017
Volume: 12
   
Issue: 3
Pages: 222 - 229
Abstract
For thin film solar cells, the efficient collection of light is a challenge, therefore an efficient light-trapping scheme, such as the textures, is required for achieving high light conversion efficien-cies. Laser texturing with a Q-switched, nanosecond pulsed Nd3+:YAG laser is used to create nano scale surface roughness in a-Si thin films that enhances light-trapping with simultaneous crystalliza-tion. Changes in surface morphology due to laser assisted texturing in air and water environments on 1-μm thick n-type amorphous silicon film deposited on p-type c-Si is observed using Optical profilometer and Atomic Force Microscopy. The light-trapping properties of textures are analyzed by optical reflectance measurements and compared with theoretical analysis. The extent of crystal-linity and the influence of structural characteristics on electronic properties are studied using I-V characterization and open circuit voltage decay method. Reduction in reflection is observed com-pared to planar surface indicating dependence of reflectance on surface textures which is in agree-ment with the theoretical analysis. After underwater annealing, efficiency of n-aSi/p-cSi solar cells is found to be increased (~ 2% to 3%) when compared to that in air and diffusion lengths of minori-ty carriers above 1-μm after laser.
About the journal
JournalJournal of Laser Micro Nanoengineering
PublisherJapan Laser Processing Society
ISSN18800688
Open AccessYes
Concepts (28)
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    Amorphous films
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    Amorphous silicon
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    Atomic force microscopy
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    Carrier lifetime
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    Electronic properties
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    Finite element method
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    Nanotechnology
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    Open circuit voltage
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    Photoelectrochemical cells
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    Photovoltaic cells
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    Pulsed lasers
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    Reflection
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    Silicon
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    Silicon solar cells
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    Solar cells
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    Surface roughness
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    Texturing
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    Thin film solar cells
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    Ultrafast lasers
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    AMORPHOUS SILICON FILM
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    DIFFUSION LENGTH
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    Laser annealing
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    Light-trapping
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    Minority carrier lifetimes
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    NANO-SCALE SURFACE ROUGHNESS
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    Open circuit voltage decays
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    Structural characteristics
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    Thin films