From the earlier works on the prediction of amorphous forming composition range (AFCR) using Miedema based model and also, on mechanical alloying experiments it has been observed that all amorphous forming compositions of a given alloy system falls within a linear band when the chemical contribution to enthalpy of the solid solution (ΔHss) is plotted against the enthalpy of mixing in the amorphous phase (ΔHamor). On the basis of this observation, a methodology has been proposed in this article to identify the AFCR of a ternary system that is likely to be more precise than what can be obtained using ΔHamor - ΔHss < 0 criterion. MA experiments on various compositions of Al-Ni-Ti system, producing amorphous, crystalline, and mixture of amorphous plus crystalline phases have been carried out and the phases have been characterized using X-ray diffraction and transmission electron microscopy techniques. Data from the present MA experiments and, also, from the literature have been used to validate the proposed approach. Also, the proximity of compositions, producing a mixture of amorphous and crystalline phases to the boundary of AFCR in the Al-Ni-Ti ternary has been found useful to validate the effectiveness of the prediction. © 2012 Elsevier B.V. All rights reserved.