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Mechanistic investigation of homogeneous hydrogen transfer from 1-phenylethanol to cyclohexanone catalyzed by dichlorotris(triphenylphosphine)- ruthenium(II)
S. Vancheesan, Jayaraman Rajaram, Joseph C. Kuriacose
Published in
Volume: 20
Issue: 2
Pages: 169 - 173
In the homogeneous hydrogen transfer from 1-phenyl-ethanol(D) to cyclohexanone(A) catalyzed by RuCl2(PPh3)3(C) in diphenyl ether as solvent at 140 °C the order of addition of donor, acceptor and catalyst have a pronounced effect on the rate of the reaction. An induction period is observed. The experimental observations correspond to the rate expression:. Initial rate = {A figure is presented} where [C]t is the total concentration of catalyst in the system. © 1983.
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JournalJournal of Molecular Catalysis
Open AccessNo
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    Chemical reactions - hydrogenation
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