The influence of the suspender on the evaporation of droplets under quiescent atmospheric conditions was studied experimentally using pendant droplets of ethanol (volatile) and water (non-volatile). Conducting and non-conducting suspenders of different materials and configurations (a steel needle, glass needle, steel rod, and glass rod) were evaluated. For both liquids, it is observed that the rate of evaporation is higher with steel suspenders. More importantly, for ethanol droplets, there is a difference in the evaporation rates between the needle and rod configurations of the same material. Thus, it is shown for the ethanol droplet that the configuration (needle versus solid rod) also plays a role in the evaporation process, apart from the material. The water droplet does not show this dependence. Visualization of internal flow and heat transfer calculations explain this observation. The results will be useful in choosing an appropriate suspender while using the pendant droplet method for studying complex interactions in an evaporating droplet. © 2019 Elsevier Masson SAS

T. N. C. Anand

Department of Mechanical Engineering

Shamit Bakshi

N. Srivathsan

Drop formation

Ethanol

Evaporation

Glass

Natural convection

Needles

Atmospheric conditions

ETHANOL DROPLET

EVAPORATION PROCESS

Evaporation rate

Internal Flows

ROD CONFIGURATIONS

SUSPENDED DROPLETS

Water droplets

Heat transfer

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IIT Madras

International Journal of Thermal Sciences

The behavior of droplets of urea-water-solution (UWS) evaporating under the influence of a hot stream of air was investigated experimentally, under temperatures ranging from 100°C to 400°C. The droplets were suspended on a glass microfiber to minimize the influence of heat conduction, through the fiber, on the evaporation rate of the droplet. The flow rate of air, under all experimental conditions, was measured and these data were used to estimate the average velocity of air around the droplet. Experiments were also conducted on droplets of pure water and the results were compared. The initial mass fraction of urea, in the solution, did not appear to have a significant effect on the evaporation constant, but it did affect a few essential aspects of the evaporation behavior. The evaporation of water droplets was in accordance with the d2 law at all temperatures, whereas the evaporation of UWS droplets was ambient-temperature dependent. © 2019 American Institute of Chemical Engineers

AIChE Journal

Experimental investigation of the evaporation behavior of urea-water-solution droplets exposed to a hot air stream

It is known from recent studies that evaporation induces flow around a droplet at atmospheric conditions. This flow is visible even for slowly evaporating liquids like water. In the present study, we investigate the influence of the ambient gas on the evaporating droplet. We observe from the experiments that the rate of evaporation at atmospheric temperature and pressure decreases in a heavier ambient gas. The evaporation-induced flow in these gases for different liquids is measured using particle image velocimetry and found to be very different from each other. However, the width of the disturbed zone around the droplet is seen to be independent of the evaporating liquid and the size of the needle (for the range of needle diameters studied), and only depends on the ambient gas used. © 2019 Author(s).

Physics of Fluids

Evaporation-induced flow around a droplet in different gases

Optofluidic manipulation using lasers and colloidal systems have immense applications in microscale thermofluidic devices. The present study analyses the effect of laser as an external optical source in modulating the evaporation characteristics of pendent nanofluid microdroplets (which are free from substrate effects) so as to capture the physics behind the interfacial mass transport. The study analyses the effect of the power of laser, nature and concentration of the particle on evaporation rate of the complex fluids. Evidence of internal circulation was observed with Particle Image Velocimetry (PIV) technique in colloidal systems which together with the volumetric heat generation due to laser irradiation can be attributed to be the cause behind the enhanced evaporation rate. The nanoparticles are observed to efficiently convert the energy of radiant photons to heat while water is observed to show poor evaporative performance under laser irradiation. Theoretical analysis of the evaporation rate with the classical diffusion driven evaporation model is found to fall short in predicting the evaporation rate in colloidal systems, even in the absence of laser irradiation. Thermal Marangoni and Rayleigh numbers are calculated from the theoretical examination and are found not potent enough to induce the circulation in such systems which could improve evaporation. Hence the observed weak internal circulation can be attributed to the solutal Marangoni arising out of the local concentration gradients of nanoparticles in the droplet and the enhanced Thermophoretic drift and Brownian dynamics of the nanoparticles. Also the enhancement in the diffusion coefficient and its strong dependence with the particle concentration is also contributing to the enhancement in enhanced evaporation rate in nanocolloidal systems. The augmentation in the evaporative process under laser radiation is found to be governed majorly by the optical heat generation with weak solutal Marangoni and a scaling model is able to accurately predict the experimental observations. The present findings could have implications in modulation of thermofluidic and species transport phenomena in microscale devices. © 2017 Elsevier Ltd

International Journal of Heat and Mass Transfer

Optical thermogeneration induced enhanced evaporation kinetics in pendant nanofluid droplets

To elucidate the pure physics of evaporation which is free from surface effects, the pendant mode of evaporation is employed in the present study. The present study brings out the evaporation kinetics of a combined surfactant and nanoparticle colloidal system. We also segregate the contributing effects of surfactants alone, particle alone, and the combined effect of surfactant and particles in modulating the evaporation kinetics. It is observed that the rate of evaporation is a strong function of the particle concentration for nanocolloidal suspensions of particle alone and concentration of surfactant molecules up to the micellar concentration and thereafter insensitive to concentration for an aqueous surfactant solution. The combined colloidal system of nanoparticles and surfactant exhibited the maximum evaporation rate, and the rate is a strong function of the concentration of both the particle and surfactant. The theoretical classical diffusion-driven evaporation falls short of the experimentally observed evaporation rate in aqueous surfactant and colloidal solutions. Evidence of convective currents was observed in flow visualization studies in aqueous surfactant solutions, nanocolloidal solution of particle alone, and an oscillatory convective circulation in a combined surfactant-impregnated nanocolloidal solution. Thermal Marangoni and Rayleigh numbers are calculated from the theoretical examination and are found not potent enough to induce strong circulation currents in such systems from a stability map. Scaling analysis of solutal Marangoni is observed to be capable of inducing circulation from a stability map in all the systems and the enhanced thermophoretic drift and Brownian dynamics, and enhancement in the diffusion coefficient of the nanoparticles is also contributing to the enhanced evaporation rate for only nanocolloidal solutions. The oscillatory convective current arising out of two opposing driving potential enhances the evaporation rate of surfactant-impregnated nanocolloids. The present findings could reveal the effect of surfactants in tuning the evaporation rate of colloidal solutions. © 2018 American Physical Society.

Physical Review Fluids

Oscillatory solutothermal convection-driven evaporation kinetics in colloidal nanoparticle-surfactant complex fluid pendant droplets

Studies on the evaporation of suspended microlitre droplets under atmospheric conditions have observed faster evaporation rates than the theoretical diffusion-driven rate, especially for rapidly evaporating droplets such as ethanol. Convective flow inside rapidly evaporating droplets has also been reported in the literature. The surrounding gas around the evaporating droplet has, however, been considered to be quiescent in many studies, the validity of which can be questioned. In the present work, we try to answer this question by direct experimental observation of the flow. The possible causes of such a flow are also explored. © 2015 AIP Publishing LLC.

Fulltext

Evaporation-induced flow around a pendant droplet and its influence on evaporation

Evaporation of a single droplet of a pure liquid in a confined chamber under atmospheric ambient condition is expected to be purely controlled by the rate of diffusion of the vapor into the surrounding. But, it is seen from the experimental results presented in this paper that for several liquids the process is faster than a theoretical estimate of the diffusion-driven process. It is seen from the visualization inside the droplet that these liquids exhibit intense internal circulation during evaporation. From a scaling analysis the temperature variations within the droplet due to surface traction and buoyancy-driven convection during evaporation is estimated. Marangoni and Rayleigh numbers are also obtained from these estimates. The values of these numbers indicate that Marangoni convection aided by buoyancy is probably the reason for the internal circulation induced within the droplet. The average velocity of the internal circulation is measured and is found to compare well with the velocity scale for Marangoni convection. © 2012 Elsevier Ltd.

International Journal of Multiphase Flow

Internal circulation in a single droplet evaporating in a closed chamber

An analysis of the droplet support fiber effect on the evaporation process

Influence of the suspender in evaporating pendant droplets

Journal	Data powered by TypesetInternational Journal of Thermal Sciences
Publisher	Data powered by TypesetElsevier Masson SAS
ISSN	12900729
Open Access	No