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In situ synthesized TiB-TiN reinforced Ti6Al4V alloy composite coatings: Microstructure, tribological and in-vitro biocompatibility
Mitun Das, Kaushik Bhattacharya, Stanley A. Dittrick, Chitra Mandal, Vamsi Krishna Balla, , Amit Bandyopadhyay, Indranil Manna
Published in Elsevier
2014
PMID: 24121827
Volume: 29
   
Pages: 259 - 271
Abstract
Wear resistant TiB-TiN reinforced Ti6Al4V alloy composite coatings were deposited on Ti substrate using laser based additive manufacturing technology. Ti6Al4V alloy powder premixed with 5. wt% and 15. wt% of boron nitride (BN) powder was used to synthesize TiB-TiN reinforcements in situ during laser deposition. Influences of laser power, scanning speed and concentration of BN on the microstructure, mechanical, in vitro tribological and biological properties of the coatings were investigated. Microstructural analysis of the composite coatings showed that the high temperature generated due to laser interaction with Ti6Al4V alloy and BN results in situ formation of TiB and TiN phases. With increasing BN concentration, from 5. wt% to 15. wt%, the Young's modulus of the composite coatings, measured by nanoindentation, increased from 170±5. GPa to 204±14. GPa. In vitro tribological tests showed significant increase in the wear resistance with increasing BN concentration. Under identical test conditions TiB-TiN composite coatings with 15. wt% BN exhibited an order of magnitude less wear rate than CoCrMo alloy-a common material for articulating surfaces of orthopedic implants. Average top surface hardness of the composite coatings increased from 543±21. HV to 877±75. HV with increase in the BN concentration. In vitro biocompatibility and flow cytometry study showed that these composite coatings were non-toxic, exhibit similar cell-materials interactions and biocompatibility as that of commercially pure titanium (CP-Ti) samples. In summary, excellent in vitro wear resistance, high stiffness and suitable biocompatibility make these composite coatings as a potential material for load-bearing articulating surfaces towards orthopaedic implants. © 2013 Elsevier Ltd.
About the journal
JournalData powered by TypesetJournal of the Mechanical Behavior of Biomedical Materials
PublisherData powered by TypesetElsevier
ISSN17516161
Open AccessNo
Concepts (52)
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    Biological properties
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    CELL-MATERIALS INTERACTIONS
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    COMMERCIALLY PURE TITANIUMS
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    LASER PROCESS
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    LASER-BASED ADDITIVE MANUFACTURING
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    LOAD-BEARING
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    Microstructural analysis
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    TITANIUM BORIDE
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    Alloys
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    Biocompatibility
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    Elastic moduli
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    Manufacture
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    Microstructure
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    Reinforcement
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    Substrates
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    Titanium
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    Titanium nitride
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    Toxic materials
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    Tribology
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    Wear of materials
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    Wear resistance
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    Composite coatings
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    Alloy
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    TITANIUM BORIDE
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    Titanium derivative
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    Unclassified drug
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    Article
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    Biomechanics
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    Concentration (parameters)
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    Controlled study
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    Flow cytometry
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    High temperature
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    Human
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    Human cell
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    In vitro study
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    Laser
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    Material coating
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    ORTHOPEDIC IMPLANT
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    Priority journal
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    YOUNG MODULUS
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    Laser processing
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    LOAD-BEARING IMPLANTS
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    TITANIUM BORIDE
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    Wear
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    Biocompatible materials
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    Boron compounds
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    Cell line
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    Humans
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    Materials testing
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    Mechanical processes
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    Osteoblasts
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    Surface properties