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Fluoro alcohol as reaction medium: One-pot synthesis of β-hydroxy sulfoxides from epoxides
, Bonnet-Delpon D., Bégué J.-P.
Published in Elsevier Science
2000
Volume: 41
   
Issue: 16
Pages: 2895 - 2898
Abstract
β-Hydroxy sulfoxides were obtained in one-pot synthesis by the ring opening of oxiranes with thiols in hexafluoroisopropanol (HFIP) without any catalyst, followed by in situ oxidation under neutral conditions. The reaction is anti-selective. β-Hydroxy sulfoxides were transformed by pyrolysis in the corresponding allylic alcohols. (C) 2000 Elsevier Science Ltd.
About the journal
JournalData powered by TypesetTetrahedron Letters
PublisherData powered by TypesetElsevier Science
ISSN0040-4039
Open AccessNo