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Enantioselective fluorination of aliphatic cyclic and acyclic β-ketoesters was achieved in excellent yield (up to 98%) with moderate to good enantioselectivities (up to 86% ee) using tartrate derived bidentate bioxazoline-Cu(II) complexes. This is the first report of a bioxazoline which forms a 5-membered chelate inducing enantioselectivity in the asymmetric fluorination of β-ketoesters.
Journal | Data powered by TypesetTetrahedron Asymmetry |
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Publisher | Data powered by TypesetElsevier |
ISSN | 0957-4166 |
Open Access | No |