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Electrochemical reduction of 2-nitrobenzidine in methanol-water mixtures
S. Aravamuthan, M. S. Sashidar, Chatty Kalidas, Chittoor Sivaramakrishnan Venkatachalam
Published in Springer India
Volume: 97
Issue: 3-4
Pages: 395 - 401
The electroreduction of 2-nitrobenzidine (2-NB) in buffered methanol-water mixtures in the composition range 20-80% (v/v) and pH range 2.80-12.00 gave a single six-electron diffusion-controlled irreversible wave. On the basis of the results obtained, a diphenoquinone-diimine intermediate is suggested in the mechanism of 2-NB reduction in methanol-water mixtures. © 1986 Indian Academy of Sciences.
About the journal
JournalData powered by TypesetProceedings of the Indian Academy of Sciences - Chemical Sciences
PublisherData powered by TypesetSpringer India
Open AccessNo