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Contact angle and detachment energy of shape anisotropic particles at fluid-fluid interfaces
Thriveni G. Anjali,
Published in Academic Press Inc.
2016
Volume: 478
   
Pages: 63 - 71
Abstract
The three phase contact angle of particles, a measure of its wettability, is an important factor that greatly influences their behaviour at interfaces. It is one of the principal design parameters for potential applications of particles as emulsion/foam stabilizers, functional coatings and other novel materials. In the present work, the effect of size, shape and surface chemistry of particles on their contact angle is investigated using the gel trapping technique, which facilitates the direct visualization of the equilibrium position of particles at interfaces. The contact angle of hematite particles of spherocylindrical, peanut and cuboidal shapes, hematite-silica core-shell and silica shells is reported at a single particle level. The spherocylindrical and peanut shaped particles are always positioned with their major axis parallel to the interface. However, for cuboidal particles at air-water as well as decane-water interfaces, different orientations namely - face-up, edge-up and the vertex-up - are observed. The influence of gravity on the equilibrium position of the colloidal particles at the interface is studied using the hematite-silica core-shell particles and the silica shells. The measured contact angle values are utilized in the calculations of the detachment and surface energies of the hematite particles adsorbed at the interface. © 2016 Elsevier Inc.
About the journal
JournalJournal of Colloid and Interface Science
PublisherAcademic Press Inc.
ISSN00219797
Open AccessNo
Concepts (37)
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    Air
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    ANISOTROPIC FLUIDS
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    Anisotropy
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    Contact angle
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    Emulsification
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    Fluidity
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    Hematite
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    Interfacial energy
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    OILSEEDS
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    Protective coatings
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    Shells (structures)
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    Silica
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    Surface chemistry
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    Surface tension
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    Anisotropic particles
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    DETACHMENT/ATTACHMENT ENERGY
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    DIRECT VISUALIZATION
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    EQUILIBRIUM POSITIONS
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    Fluid fluid interfaces
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    GEL TRAPPING TECHNIQUE
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    SILICA CORE SHELL PARTICLES
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    THREE PHASE CONTACTS
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    Phase interfaces
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    Decane
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    Ferric oxide
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    Silicon dioxide
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    Stabilizing agent
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    Water
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    Article
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    Chemistry
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    Dissolution
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    Emulsion
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    Energy
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    Particle size
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    Priority journal
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    Synthesis
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    Wettability