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Complete Reduction of Ilmenite by CO in Chemical Looping Combustion - Multistep Kinetic Model Approach
V. Prabakaran,
Published in American Chemical Society
2019
Volume: 33
   
Issue: 7
Pages: 6585 - 6590
Abstract
The complete reduction behavior of iron oxide to iron in ilmenite ore was studied thermogravimetrically in the temperature range of 900-1100 °C by 30% CO concentration over 200 min. The rate of reduction curves moved from deceleratory to sigmoidal-shape (knee shape) behavior after about one-third of conversion. Analysis of data reveals that the reduction of ilmenite ore occurs by three independent parallel reduction steps, namely, Fe2O3 → Fe3O4, Fe3O4 → FeO, and FeO → Fe. The conversion data have been correlated for the first time using a multistep kinetic model derived from the Johnson-Mehl-Avrami approach. The apparent activation energies of these three steps have been estimated to be 46.32, 63.14, and 46.07 kJ/mol. The model is able to predict reduction data of complete conversion of ilmenite ore. © 2019 American Chemical Society.
About the journal
JournalData powered by TypesetEnergy and Fuels
PublisherData powered by TypesetAmerican Chemical Society
ISSN08870624
Open AccessNo
Concepts (18)
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    Activation energy
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    Combustion
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    Hematite
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    ILMENITE
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    IRON ORE REDUCTION
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    Kinetic parameters
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    Kinetic theory
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    Magnetite
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    ORE ANALYSIS
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    Analysis of data
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    Apparent activation energy
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    Chemical looping combustion
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    Co concentrations
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    Johnson-mehl-avrami
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    Rate of reduction
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    REDUCTION BEHAVIOR
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    Temperature range
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    Data reduction