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Cobalt(III)-Catalyzed Allylation of Arene C–H Bonds
Kuppan Ramachandran,
Published in Wiley-VCH Verlag
Volume: 2017
Issue: 27
Pages: 3965 - 3968
The cobalt(III)-catalyzed chelation-assisted allylation of arene C–H bonds was accomplished by employing allyl carbonates. The important features of the present reaction include the use of directing groups such as pyrazoles and pyridines, wide functional-group tolerance, and the synthesis of various allylated (hetero)arenes in good to excellent yields. On the basis of the observations, a plausible mechanism is also proposed involving the formation of a π-allyl species. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
About the journal
JournalData powered by TypesetEuropean Journal of Organic Chemistry
PublisherData powered by TypesetWiley-VCH Verlag
Open AccessNo