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Articles
Chiral cobalt-catalyzed enantioselective aerobic oxidation of α-hydroxy estersPublished in
2010
DOI: 10.1039/c0cc01917h
PMID: 20820516
Volume: 46
Issue: 38
Pages: 7235 - 7237
A chiral cobalt-catalyzed enantioselective aerobic oxidative kinetic resolution of (±)-α-hydroxy esters, using molecular oxygen as a sole oxidant, is reported and a maximum of selectivity factor (s) 31.9 was achieved with >99% enantiomeric excess for unreacted α-hydroxy esters. © 2010 The Royal Society of Chemistry.
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About the journal
| Journal | Chemical Communications |
|---|---|
| ISSN | 13597345 |
| Open Access | No |
Authors (1)
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Concepts (14)
Cobalt- Ester derivative
- Oxygen
- Article
- Chirality
- Enantiomer
- Enantioselectivity
- Kinetics
- Oxidation
- Catalysis
- Esters
- Hydroxyl radical
- Oxidation-reduction
- Stereoisomerism
