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Chemistry of group 9 dimetallaborane analogues of octaborane(12)
Published in Royal Society of Chemistry
2015
Volume: 44
   
Issue: 2
Pages: 669 - 676
Abstract
We report the synthesis, isolation and structural characterization of several moderately air stable nido-metallaboranes that represent boron rich open cage systems. The reaction of [Cp∗CoCl]2, (Cp∗ = η5-C5Me5), with [BH3·thf] in toluene at ice cold temperature, followed by thermolysis in boiling toluene produced [(Cp∗Co)B9H13], 1 [(Cp∗Co)2B8H12], 2 and [(Cp∗Co)2B6H10] 3. Building upon our earlier reactivity studies on rhodaboranes, we continue to explore the reactivity of dicobalt analogues of octaborane(12) cluster 3 with [Fe2(CO)9] and [Ru3(CO)12] at ambient conditions that yielded novel fused clusters [Fe2(CO)6(Cp∗Co)2B6H10], 4 and [Ru4(CO)11(Cp∗Co)2B3H3], 5 respectively. In an attempt to synthesize a heterometallic metallaborane compound we performed the reaction of [(Cp∗Rh)2B6H10], 6 with [Cp∗IrH4] that yielded a Ir-Ir double bonded compound [(Cp∗Ir)2H3][B(OH)4], 7. All the new compounds have been characterized by IR, 1H, 11B, 13C NMR spectroscopy, and the molecular structures were unambiguously established by X-ray diffraction analysis. This journal is © The Royal Society of Chemistry.
About the journal
JournalData powered by TypesetDalton Transactions
PublisherData powered by TypesetRoyal Society of Chemistry
ISSN14779226
Open AccessYes
Concepts (16)
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    Cobalt
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    Iridium
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    Iron compounds
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    Nuclear magnetic resonance spectroscopy
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    Synthesis (chemical)
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    Toluene
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    X ray diffraction analysis
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    AIR STABLE
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    Ambient conditions
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    CAGE SYSTEMS
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    COLD TEMPERATURES
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    Heterometallics
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    Metallaboranes
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    Reactivity studies
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    Structural characterization
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    Cobalt compounds