The present study describes the Computational Fluid Dynamics (CFD) modeling of two phase flow boiling for the prediction of Critical Heat Flux (CHF) and its location in a tube, an annulus and a 4×4 rod bundle geometry. A number of different closure models employed for the calculation of the interface momentum exchange are assessed based on a comparison of wall temperature predictions against available experimental data. From detailed and systematic validations, a mean relative error of 15% and 7% for tube and annulus cases respectively was noticed. These simulations identify the CHF location in an annulus and in a rod bundle. The wall temperature variations are predicted for the concentric and eccentric annulus as well as a 4×4 rod bundle geometry. Eccentricity was found to promote early occurrence of CHF in the narrow gap and delay in the wide gap regions. For the 4×4 rod bundle considered, the corner rod facing the pressure tube was found to have an early shoot up in the wall temperature. © 2019