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Alkylation of naphthalene with alcohols over acidic mesoporous solids
Balasubramanian Viswanathan, Thirukkallam Kanthadai Varadarajan
Published in
2005
Volume: 226
   
Issue: 2
Pages: 155 - 163
Abstract
Mesoporous cubic MCM-48 was synthesized at a lower concentration of the surfactant. XRD, N 2 adsorption and electron microscopic studies confirmed the formation of cubic phase. Spectroscopic and electron spin resonance techniques confirmed the presence of heteroatom within the framework. The catalytic activities of various acid catalysts have been examined for vapour phase alkylation of naphthalene with alcohols and these studies revealed that aluminium substituted cubic MCM-48 was more active compared to Fe-MCM-48, Al-MCM-41 and H-Y zeolite. © 2004 Elsevier B.V. All rights reserved.
About the journal
JournalJournal of Molecular Catalysis A: Chemical
ISSN13811169
Open AccessNo
Concepts (38)
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    ACIDIC MESOPOROUS SOLIDS
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    Catalytic activities
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    Heteroatoms
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    Acidity
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    Adsorption
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    Alcohols
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    Alkylation
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    Catalysis
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    Concentration (process)
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    Electron microscopy
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    Paramagnetic resonance
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    Surface active agents
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    Synthesis (chemical)
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    Vapors
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    X ray diffraction analysis
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    Naphthalene
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    Acid
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    Alcohol
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    Aluminum
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    Chemical compound
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    Iron
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    MCM 41
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    MCM 48
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    Nitrogen
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    Surfactant
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    Unclassified drug
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    Zeolite
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    Article
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    Atom
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    Catalyst
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    Concentration (parameters)
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    Electron spin resonance
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    Porosity
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    Solid
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    Spectroscopy
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    Synthesis
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    Vapor
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    X ray diffraction