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A new strategy for the synthesis of 2-aryl- and 2-heteroaryl fluoroarenes has been developed. An intermolecular domino Grignard-coupling–fluorination sequence affords a range of 2-fluorobiaryls from aryl bromides under mild conditions. This methodology can be further extended to the synthesis of 2′-aryl-2-fluorobiphenyls.
Journal | Data powered by TypesetChemistry: An Asian Journal |
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Publisher | Data powered by TypesetWiley |
Open Access | No |