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Unravelling dynamical behavior of intergranular glassy films in Si3N4 ceramics during in-situ heating: Exit wave reconstruction insights
Chiranjit Roy, Piu Rajak, , Pritam Banerjee, Sathish Kumar S
Published in Elsevier Ltd
2020
Volume: 818
   
Abstract
Dynamical behavior of intergranular glassy films (IGFs) in undoped and Lu2O3– MgO doped Si3N4 ceramics was studied by reconstructing complex-valued exit wave using focal series bright field images acquired at different temperatures during heating in-situ within transmission electron microscope (TEM). Width and value of retrieved phase change of the complex-valued exit wave across the IGFs were used to study changes that occur during in–situ heating until 950 °C. Results revealed that the IGF of an undoped sample maintains its equilibrium configuration. In the case of doped one, the phase difference between adjacent grains with IGF decreases but at the same time width of IGF increases during in-situ heating. Collectively, these two trends are indicative of the change in the mean inner potential of IGF during heating which in turn reveals that IGF in Lu2O3– MgO doped Si3N4 does not maintain equilibrium configuration. Mean inner potential differences between IGF and adjacent grain of doped samples at room temperature exhibit a higher value than that of the undoped one due to rare earth element segregation within IGF. This might be the cause of the difference in the dynamical behavior of IGFs observed in the present study. © 2019 Elsevier B.V.
About the journal
JournalData powered by TypesetJournal of Alloys and Compounds
PublisherData powered by TypesetElsevier Ltd
Open AccessNo
Concepts (17)
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    Dynamics
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    Glass
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    Heating
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    Lutetium compounds
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    Magnesia
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    Rare earths
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    Textures
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    Transmission electron microscopy
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    BRIGHT-FIELD IMAGES
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    Dynamical behaviors
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    Equilibrium configuration
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    EXIT WAVES
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    IN-SITU HEATING
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    INTERGRANULAR GLASSY FILMS
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    MEAN INNER POTENTIAL
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    SI3N4
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    Silicon compounds