Cannan Booma

Kalapattukuppuswamy Kuppuswamy B. Balasubramanian

glycoside

article

priority journal

reaction analysis

stereochemistry

synthesis

IIT Madras is a public technical and research university located in Chennai, Tamil Nadu. Founded in 1959, it is recognised as an Institute of National Importance.

IIT Madras has been ranked as the top engineering institute in India for four years in a row by the National Institutional Ranking Framework of the MHRD

It currently offers undergraduate, postgraduate and research degrees across 16 disciplines in Engineering, Sciences, Humanities and Management. About 596 faculty belonging to science and engineering departments and centres of the Institute are engaged in teaching, research and industrial consultancy.

IIT Madras

Unexpected C3 arylation of 3,4,6-tri-O-methyl-2-C-formylglycals : a simple route to 3-C-arylhexoses

Tetrahedron Letters

Readily available 3,4,6-tri-O-acetyl-D-glucal was converted to 2,6-anhydro-5,7-O-benzylidene-1,3,4-trideoxy-D-arabino-hept-3-enitol, a methyl C-glycosylic compound. Cyclopropanation of 4,6-O-benzylidene-D-glucal, followed by tributylstannyl radical-mediated regioselective ring opening of the 1,2-cyclopropano sugar led to a 2,6-anhydro-1-deoxyheptose, (a "methyl C-β-D-glycoside"). The stereochemistry of the 1,2-cyclopropano sugar and the "methyl C-glycoside" were confirmed by single-crystal X-ray diffraction studies. © 2002 Elsevier Science Ltd. All rights reserved.

Carbohydrate Research

Stereoselective synthesis of a C-glycosylic compound (a "methyl C-glycoside") through a regioselective free-radical ring-opening reaction. A single-crystal X-ray structure determination

Benezit Dictionary of Artists

Imamura, Yukio

CHEMICAL & PHARMACEUTICAL BULLETIN

Identification of the aglycon part of vineomycin A1 with aquayamycin.

Journal	Tetrahedron Letters
ISSN	00404039
Open Access	No