Thermal decomposition of an intimate mixture of thallium(I) perchlorate and chromium(III) oxide revealed that chromium(III) oxide lowers the decomposition temperature of thallium(I) perchlorate and is oxidized into hexavalent state to give thallium(I) dichromate. The thermal decomposition was followed by constant temperature heating, thermogravimetry and differential thermal analysis. The reaction products were characterized by chemical analysis, X-ray diffraction and infrared spectral measurements. © 1974.

M. Ramakrishna Udupa

G. K. Ramachandra

IIT Madras is a public technical and research university located in Chennai, Tamil Nadu. Founded in 1959, it is recognised as an Institute of National Importance.

IIT Madras has been ranked as the top engineering institute in India for four years in a row by the National Institutional Ranking Framework of the MHRD

It currently offers undergraduate, postgraduate and research degrees across 16 disciplines in Engineering, Sciences, Humanities and Management. About 596 faculty belonging to science and engineering departments and centres of the Institute are engaged in teaching, research and industrial consultancy.

IIT Madras

Thermal decomposition of thallium(I) perchlorate in presence of chromium(III) oxide

Thermochimica Acta

The reaction between potassium iodate and molybdenum(VI) oxide in mixtures of different mole ratios has been investigated employing TG and DTA techniques in static air atmosphere. The products are characterised by infrared spectroscopy, chemical analysis and X-ray diffraction studies. The studies indicate the formation of mono-, di-, tri- and tetramolybdates of potassium from mixtures with 2:1, 1:1, 2:3 and 1:2 mole ratios of KlO3:MoO3. The kinetics of the reaction was followed and the energy of activation values were computed. © 1989 Wiley Heyden Ltd., Chichester and Akadémiai Kiadó, Budapest.

Journal of Thermal Analysis

Solid state reactions in the potassium iodate and molybdenum(VI) oxide system

A study of the thermal decomposition of intimate mixtures of different molar ratios of potassium perchlorate and chromium(III) oxide, and potassium perchlorate and nickel(II) chromite(III) was conducted employing thermogravimetry, differential thermal analysis, chemical analysis, infrared spectroscopy and X-ray diffraction analysis. Upon heating to 400°C Cr(III), in 2:1 molar ratios, is oxidized to potassium dichromate. Only a stoichiometric amount of Cr(III) was oxidized from molar ratios less than 2:1, leaving behind excess Cr2O3 and NiCr2O4 whereas from molar ratios greater than 2:1, Cr(III) was completely oxidized and the excess KClO4 started decomposing around 410°C which is much below the decomposition temperature of pure KClO4. © 1975.

Thermal decomposition of potassium perchlorate in presence of chromium(III) oxide and nickel(II) chromite(III)

Chemischer Informationsdienst

ChemInform Abstract: THALLIUM(I)-URANATES(VI)

Journal of Inorganic and Nuclear Chemistry

On the reaction between molten lithium perchlorate and chromium(III) oxide

Spectrochimica Acta

Infrared absorption study of metal oxides in the low frequency region (700-240 cm−1)

Zeitschrift für Kristallographie - Crystalline Materials

36. Die kubische Hochtemperaturstruktiir einiger Perchlorate

Journal	Thermochimica Acta
ISSN	00406031
Open Access	No