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The hemi-adduct of bis(diethyldithiocarbamato-S,S′)tellurium(II) with 4,4′-bipyridyl
, M. Ramakrishna Udupa, Gopalaswamiengar Aravamudan
Published in Blackwell Munksgaard
1996
Volume: 52
   
Issue: 3
Pages: 707 - 709
Abstract
In the structure of bis(diethyldithiocarbamato-S,S′)-tellurium(II)-4,4′-bipyridyl (2/1), [Te(C5H10NS2)2].-1/2C10H 8N2, the bipyridyl molecule was found to bridge two bis(diethyldithiocarbamato)tellurium moieties centrosymmetrically, i.e. μ-(4,4′-bipyridyl-N:N′)-bis(diethyl-dithiocarbamato-S,S′) tellurium. The N atom of the bipyridyl is very weakly coordinated to tellurium and this is the first instance of Te-N coordination observed in a tellurium-dithiocarbamate complex. Each Te atom has an unusual planar-pentagonal arrangement of ligands around it.
About the journal
JournalActa Crystallographica Section C: Crystal Structure Communications
PublisherBlackwell Munksgaard
ISSN01082701
Open AccessNo
Concepts (18)
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    Aromatic compounds
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    Atoms
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    Chemical bonds
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    Molecular structure
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    Molecules
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    Nitrogen
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    Organometallics
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    Sulfur
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    Tellurium
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    ADDUCT ISOLATION
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    Bipyridyl
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    BIS DIETHYLDITHIO CARBAMATE TELLURIUM
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    Bond length
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    CENTROSYMMETRY
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    DITHIOCARBAMATE
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    Ligands
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    Structure determination
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    Tellurium compounds