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The first mixed iodide-dithiocarbamate complex of selenium(II): Catena-poly[[(di-n-propyldithiocarbamato-S,S′)selenium(II)]-μ-iodo]
, Gopalaswamiengar Aravamudan, M. Ramakrishna Udupa
Published in Blackwell Munksgaard
Volume: 55
Issue: 8
Pages: 1320 - 1322
The title compound, [SeI(C7H14NS2)]n, was prepared by the oxidative displacement of one of the dithiocarbamates in bis(di-n-propyldithiocarbamato)-selenium(II) using iodine. This complex has a polymeric structure, with the central Se atoms bridged by the iodine ions. The geometry around each Se atom is planar trapezoidal (SeS2I2), with Se - I distances of 3.124(2) and 3.232 (I) Å. This is the first example of a mixed iodide-dithiocarbamate complex of selenium(II).
About the journal
JournalActa Crystallographica Section C: Crystal Structure Communications
PublisherBlackwell Munksgaard
Open AccessYes