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Synthesis and Photocatalytic Study of Ferrocenium Ion Incorporated Lacunary Keggin Hybrid Material
Published in Wiley-Blackwell
Volume: 4
Issue: 36
Pages: 10884 - 10894
In the present work, we report the synthesis of inorganic-organic hybrid material of molecular formula ((C4H9)4N)2[H3(Fe(C5H5)2)2PW11O39] � 7H2O abbreviated as TBAFcPW11. This hybrid material has large surface area (142 m2 g−1) and shows photocatalytic activity due to the synergistic effect of photoexcitation property of polyoxometalate cluster and Fe2+/Fe3+ redox pair. It is a floating hybrid photocatalytic material capable of remediating organic pollutants, rhodamine B and p-nitrophenol. Optimum conditions for photocatalytic degradation and extent of mineralization have been established by varying the reaction conditions and mineralization studies. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
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PublisherData powered by TypesetWiley-Blackwell
Open AccessNo