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Syntheses, structure and rare earth metal photoluminescence of new and known isostructural A2Mo4Sb2O18 (A=Ce, Pr, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) compounds
Published in
2011
Volume: 184
   
Issue: 4
Pages: 735 - 740
Abstract
Nine new A2Mo4Sb2O18 (A=Ce, Pr, Eu, Tb, Ho, Er, Tm, Yb, Lu) compounds have been synthesized by solid-state reactions. They are isostructural with six reported analogues of yttrium and other lanthanides and the monoclinic unit cell parameters of all fifteen of them vary linearly with the size of A3 ion. Single crystal X-ray structures of eight A2Mo4Sb2O18 (A=Ce, Pr, Eu, Gd, Tb, Ho, Er, Tm) compounds have been determined. Neat A 2Mo4Sb2O18 (A=Pr, Sm, Eu, Tb, Dy, Ho, Er, Tm) compounds exhibit characteristic rare earth metal photoluminescence. © 2011 Elsevier Inc. All rights reserved.
About the journal
JournalJournal of Solid State Chemistry
ISSN00224596
Open AccessNo
Concepts (26)
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    Isostructural
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    Lanthanides
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    MOLYBDOANTIMONITES
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    MONOCLINIC UNITS
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    Rare earth metals
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    Single crystal x-ray structures
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    Solid-state structures
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    Cerium
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    Diffraction
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    Dysprosium compounds
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    Erbium
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    Erbium compounds
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    Europium
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    Gadolinium
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    Holmium
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    Molybdenum
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    Photoluminescence
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    Rare earths
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    Single crystals
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    Solid state reactions
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    Terbium
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    X ray diffraction
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    X rays
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    Ytterbium
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    Yttrium
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    EUROPIUM COMPOUNDS