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Syntheses, structure and intercalation properties of low-dimensional phenylarsonates, A(HO3AsC6H5)(H 2O3AsC6H5) (A = Tl, Na, K and Rb)
Bonthu Krishna Kishore Reddy,
Published in Springer India
2006
Volume: 118
   
Issue: 1
Pages: 117 - 126
Abstract
Four new low-dimensional phenylarsonates, A(HO3AsC 6H5)(H2O3AsC6H 5) (A = Tl(1), Na(2), K(3) and Rb(4)), have been synthesized and characterized by X-ray diffraction, spectroscopic and thermal studies. They crystallize in triclinic unit cells and have approximately planar arrangement of A+ ions, coordinated to oxygen atoms of phenylarsonates, on both sides. Structure of thallium phenylarsonate as determined by single crystal X-ray diffraction, is one-dimensional, whereas those of alkalimetal analogues are two-dimensional. Successful intercalation reactions of compounds 1 and 2 with primary n-alkyl amines have been demonstrated. © Indian Academy of Sciences.
About the journal
JournalData powered by TypesetJournal of Chemical Sciences
PublisherData powered by TypesetSpringer India
ISSN02534134
Open AccessYes
Concepts (10)
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    Amines
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    Molecular structure
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    Single crystals
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    Spectroscopic analysis
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    Synthesis (chemical)
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    X ray diffraction
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    LOW-DIMENSIONAL COMPOUNDS
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    ORGANIC-INORGANIC HYBRID COMPOSITES
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    PHENYLARSONATES
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    Intercalation compounds