Header menu link for other important links
X
Superparamagnetic clusters at room temperature, anomalous magnetic coercivity and spin-flop transition in novel dilute antiferromagnetic nanoparticles of La2Fe0.875Cr0.125GaO6
Ramchandra Dhal, P. Neenu Lekshmi, Dhruba Das,
Published in Elsevier B.V.
2019
Volume: 483
   
Pages: 272 - 280
Abstract
Magnetism at the nanoscale is intriguing, but that on the magnetic properties of a dilute antiferromagnetic (AFM) system is rarely studied. Presence of uncompensated spins at the lattice as well as on the nanoparticle surfaces could lead to interesting magnetic behaviour. We present the combined effect of reduction in particle size and dilution of exchange interactions on the magnetic properties of an AFM perovskite oxide. A dilute AFM compound, La2Fe0.875Cr0.125GaO6 nanoparticles (average particle size ∼ 44.5 (7) nm), has been synthesized where non-magnetic Ga-ions are introduced to interrupt the superexchange pathways. The compound crystallizes in orthorhombic structure with Pbnm space group, where Fe, Cr and Ga ions are distributed randomly in the B-site. DC magnetic studies show superparamagnetic behaviour at room temperature, spin-flop transition and a prominent hysteresis loop with sufficiently high coercivity around 6.69 kOe at ∼138 K. The analysis of thermoremanent and isothermoremanent magnetization curves reveal SPM behaviour at 300 K and 2-dimensional dilute antiferromagnetic in field like nature at 5 K. AC magnetic susceptibility analysis confirms the presence of non-interacting clusters having SPM behaviour with blocking temperature ∼280 K. Furthermore, temperature variation of coercivity shows a Gaussian nature, mainly associated with competing Dzyaloshinskii-Moriya interactions between disordered B-site ions along with strong uncompensated surface spin effects. © 2019 Elsevier B.V.
About the journal
JournalData powered by TypesetJournal of Magnetism and Magnetic Materials
PublisherData powered by TypesetElsevier B.V.
ISSN03048853
Open AccessNo
Concepts (22)
  •  related image
    Antiferromagnetism
  •  related image
    Coercive force
  •  related image
    Ions
  •  related image
    Magnetic field effects
  •  related image
    Magnetic materials
  •  related image
    Magnetic susceptibility
  •  related image
    Magnetization reversal
  •  related image
    Nanoparticles
  •  related image
    Particle size
  •  related image
    Particle size analysis
  •  related image
    Perovskite
  •  related image
    Superparamagnetism
  •  related image
    Synthesis (chemical)
  •  related image
    Ac magnetic susceptibility
  •  related image
    ANTIFERROMAGNETIC NANOPARTICLE
  •  related image
    Antiferromagnets
  •  related image
    Dzyaloshinskii-moriya interaction
  •  related image
    Orthorhombic structures
  •  related image
    SPIN-FLOP TRANSITIONS
  •  related image
    Superparamagnetic clusters
  •  related image
    Uncompensated surface spins
  •  related image
    Nanomagnetics