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Spectral evidence for the formation of active intermediates from RuCl3 and RuCl2(PPh3)3 with N-methylmorpholine N-oxide (NMO) and phenyliodosoacetate (PIA) as mild oxidants
K. Vijayasri, Jayaraman Rajaram, Joseph C. Kuriacose
Published in
Volume: 117
Issue: 2
Pages: 133 - 138
Electronic, EPR and IR spectral evidence are given for the formation of the following active species: (1) ruthenium(VIII) in ruthenium(III)-PIA system, (2) ruthenium(V) oxo species in ruthenium(III)-N- oxide system, and (3) ruthenium(II)-phosphine oxide complex in ruthenium(II) N-oxide system. Cyclic voltammetric studies also suggest the formation of Ru(V) in ruthenium(III)-N-oxide system. © 1986.
About the journal
JournalInorganica Chimica Acta
Open AccessNo