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Silver nitrate catalyzed oxidation of sulfides
Rima Das, Debashis Chakraborty
Published in
2011
   
Issue: 2
Pages: 277 - 280
Abstract
A variety of sulfides were converted into the corresponding sulfoxide derivatives with 70% tert-butyl hydroperoxide in water as the oxidant in the presence of catalytic quantity of silver nitrate. The method described has a wide range of application, does not involve cumbersome workup, exhibits chemoselectivity, and proceeds under mild reaction conditions, and the resulting products are obtained in good yields within a reasonable time. © Georg Thieme Verlag Stuttgart New York.
About the journal
JournalSynthesis
ISSN00397881
Open AccessNo
Concepts (21)
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    CATALYTIC QUANTITIES
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    Catalyzed oxidation
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    Chemo-selectivity
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    Good yield
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    Mild reaction conditions
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    Silver nitrate
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    SILVER NITRATES
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    Sulfide
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    Sulfoxide
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    TERT-BUTYLHYDROPEROXIDE
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    Nitrates
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    Oxidation
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    Silver
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    Silver alloys
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    Tert butyl hydroperoxide
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    Article
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    Catalysis
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    Chemical analysis
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    Chemical interaction
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    Chemical reaction
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    Chemical structure