Header menu link for other important links
Silver-Catalyzed Hydroboration of C-X (X = C, O, N) Multiple Bonds
, Pandey V.K., Tiwari C.S.
Published in ACS Publications
Volume: 23
Issue: 5
Pages: 1681 - 1686
AgSbF6 was developed as an effective catalyst for the hydroboration of various unsaturated functionalities (nitriles, alkenes, and aldehydes). This atom-economic chemoselective protocol works effectively under low catalyst loading, base- A nd solvent-free moderate conditions. Importantly, this process shows excellent functional group tolerance and compatibility with structurally and electronically diverse substrates (>50 examples). Mechanistic investigations revealed that the reaction proceeds via a radical pathway. Further, the obtained N,N-diborylamines were showcased to be useful precursors for amide synthesis. © 2021 American Chemical Society. All rights reserved.
About the journal
JournalOrganic Letters
PublisherACS Publications
Open AccessNo