The recent surge to explore and exploit the effect of particle shape has led to several interesting and unique observations in various diverse fields, ranging from biology to material science. To this end, the development of novel synthesis methods has contributed immensely, and has directed this exciting research on the role of particle shape in colloidal systems and other diverse fields. Furthermore, such investigations have resulted in the development of advanced materials, which are novel and multi-functional. In this article, we review recent advances in the study of suspensions containing shape anisotropic particles. In particular, we investigate those pertaining to rod-like or ellipsoidal particles and highlight recent results in three areas-evaporation driven assembly, packing, interfacial behavior and the use of these particles in emulsion stabilization. © 2013 The Royal Society of Chemistry.

Madivala Gurapa Basavaraja

Department Of Chemical Engineering

Venkateshwar Rao Dugyala

Advanced materials

Anisotropic colloids

Anisotropic particles

ELLIPSOIDAL PARTICLES

Emulsion stabilization

EVAPORATION-DRIVEN ASSEMBLY

INTERFACIAL BEHAVIORS

PACKING BEHAVIOR

Anisotropy

Colloids

Emulsification

Evaporation

Phase Transitions

Stabilization

Suspensions (fluids)

IIT Madras is a public technical and research university located in Chennai, Tamil Nadu. Founded in 1959, it is recognised as an Institute of National Importance.

IIT Madras has been ranked as the top engineering institute in India for four years in a row by the National Institutional Ranking Framework of the MHRD

It currently offers undergraduate, postgraduate and research degrees across 16 disciplines in Engineering, Sciences, Humanities and Management. About 596 faculty belonging to science and engineering departments and centres of the Institute are engaged in teaching, research and industrial consultancy.

IIT Madras

Soft Matter

Solid-stabilized emulsions commonly known as Pickering emulsions offer unique benefits such as superior stability and controlled permeability compared to conventional surfactant stabilized emulsions. In this article, the effect of pH, the electrolyte and particle concentration, homogenization speed, and volume fraction of oil on the formation, stability, and the microstructure of emulsion droplets stabilized by micron-size peanut-shaped hematite particles are investigated. The influence of surface charge of particles on emulsification is studied by varying the pH of the dispersing medium, the addition of an electrolyte or a combination of both. Stable O/W emulsions are formed only when the aqueous dispersions at intermediate pH between 4 and 11, and decane (2:1 volume ratio) are vigorously mixed. However, emulsions are not formed when the particles are highly charged that is, at pH 2 and 12. The presence of monovalent salt or high-speed homogenization assists the emulsion formation at pH 3, whereas their combination helps in emulsification at pH 2. However, neither the addition of an electrolyte nor the high-speed homogenization or their combination facilitates the formation of emulsions at pH 12. We show that the image-charge repulsion and the surface charge induced wettability change can explain the influence of both pH and salt concentrations on the formation of Pickering emulsions. Although oil-in-water emulsions typically cream because of the density difference, microscopy observations revealed the presence of a large number of small particle-covered oil droplets in the sediments of the emulsified samples. These drops are observed to be entrapped in dense-particle networks. This leads to a considerable reduction in the number of particles available for the stabilization of floating emulsion droplets and thus influences their size and surface coverage. The possibility of tailoring the stability, droplet size and, the surface coverage discussed in this article can play a crucial role in situations that demand controlled release of active components. © 2018 American Chemical Society.

Langmuir

Influence of pH and Salt Concentration on Pickering Emulsions Stabilized by Colloidal Peanuts

We report a complete suppression of the coffee-ring effect resulting in the formation of loosely packed two-dimensional particle monolayers by controlled evaporation of sessile drops containing soft microgel particles. These particulate deposits show gradual order-to-disorder transitions that are not abrupt like deposits of hard colloids. The areal coverage of the monolayer deposits can also be precisely controlled by tuning the particle concentration. The preferential adsorption of soft-microgel particles to the water-vapor interface, and their radial flow along the interface towards the drop edge facilitates the creation of the novel monolayer deposits. © 2017 The Royal Society of Chemistry.

Nanoscale

Loosely packed monolayer coffee stains in dried drops of soft colloids

The three phase contact angle of particles, a measure of its wettability, is an important factor that greatly influences their behaviour at interfaces. It is one of the principal design parameters for potential applications of particles as emulsion/foam stabilizers, functional coatings and other novel materials. In the present work, the effect of size, shape and surface chemistry of particles on their contact angle is investigated using the gel trapping technique, which facilitates the direct visualization of the equilibrium position of particles at interfaces. The contact angle of hematite particles of spherocylindrical, peanut and cuboidal shapes, hematite-silica core-shell and silica shells is reported at a single particle level. The spherocylindrical and peanut shaped particles are always positioned with their major axis parallel to the interface. However, for cuboidal particles at air-water as well as decane-water interfaces, different orientations namely - face-up, edge-up and the vertex-up - are observed. The influence of gravity on the equilibrium position of the colloidal particles at the interface is studied using the hematite-silica core-shell particles and the silica shells. The measured contact angle values are utilized in the calculations of the detachment and surface energies of the hematite particles adsorbed at the interface. © 2016 Elsevier Inc.

Journal of Colloid and Interface Science

Contact angle and detachment energy of shape anisotropic particles at fluid-fluid interfaces

In this contribution, we discuss the role of surface charge on the adsorption of shape anisotropic particles to fluid-fluid interfaces in the context of their application in particle-stabilized emulsions. Starting with a pendent aqueous drop containing nano-ellipsoids of known surface charge density suspended in an oil medium, we study the kinetics of adsorption of the ellipsoids to the water-decane interface using pendant drop tensiometry. The interfacial tension of the drop is recorded as a function of time by analyzing the shape of the drop. We show that the particles that are weakly charged readily adsorb to the water-decane interface and the adsorption behavior is influenced by the particle surface charge density. Furthermore, as the area available for the particles deposited at the interface is reduced, the interface populated with self-assembled ellipsoids shows wrinkles indicating buckling of the particle-laden interface under compression. However, the buckling is not observed if nano-ellipsoids are highly charged confirming that the particles do not adsorb to the interface when they are highly charged. This suggests that in several examples where the particles at interfaces concept is exploited, the repulsive energy barrier due to the particle surface charge plays a key role in the adsorption of particles to the interfaces. However, once the particles are adsorbed, the interfacial properties of the monolayer depend on the particle-particle interactions. Thus a combination of these interactions determines the concentration of particles at the interface, their microstructure and interfacial properties. The effect of these interactions on the quantity and size of the emulsion drops stabilized by ellipsoidal particles is also explored. © The Royal Society of Chemistry 2016.

Faraday Discussions

Nano ellipsoids at the fluid-fluid interface: Effect of surface charge on adsorption, buckling and emulsification

Cracks in a colloidal film formed by evaporation induced drying can be controlled by changing drying conditions. We show, for the first time that the crack morphologies in colloidal films are dependent on shape of constituting particles apart from the microstructure and particle assembly. In order to investigate the particle shape effect on crack patterns, monodispered spherical and ellipsoidal particles are used in sessile drop experiments. On observing the dried sessile drop we found cracks along the radial direction for spherical particle dispersions and circular crack patterns for ellipsoidal particle dispersions. The change in crack pattern is a result of self assembly of shape anisotropic particles and their ordering. The ordering of particles dictate the crack direction and the cracks follow the path of least resistance to release the excess stress stored in the particle film. Ellipsoids having different aspect ratio (∼3 to 7) are used and circular crack patterns are repeatedly observed in all experiments. © 2016 The Author(s).

Fulltext

Scientific Reports

Role of particle shape anisotropy on crack formation in drying of colloidal suspension

Chemical Reviews

Janus Particles: Synthesis, Self-Assembly, Physical Properties, and Applications

Biomacromolecules

Surfactant-Free High Internal Phase Emulsions Stabilized by Cellulose Nanocrystals

Cellulosic nanorods of various aspect ratios for oil in water Pickering emulsions

Chemistry of Materials

Simple Synthesis of Versatile Akaganéite-Silica Core–Shell Rods

Physical Review Letters

Confinement Induced Splay-to-Bend Transition of Colloidal Rods

Shape anisotropic colloids: Synthesis, packing behavior, evaporation driven assembly, and their application in emulsion stabilization

Journal	Soft Matter
ISSN	1744683X
Open Access	No