Header menu link for other important links
Self-Assembly of Molecular Cylinders from Polycarbene Ligands and AgIor AuI
, Pape Tania, Ekkehardt Hahn F.
Published in American Chemical Society (ACS)
Volume: 132
Issue: 13
Pages: 4572 - 4573

Tris- and tetrakis(imidazolium) salts react with Ag2O to give cylindrical polynuclear silver(I) complexes such as the tetrasilver derivative [Ag4(1)2](PF6)4. The silver(I) complexes undergo transmetalation with [AuCl(SMe2)] to yield homonuclear gold(I) complexes with retention of the metallosupramolecular assembly.

About the journal
JournalData powered by TypesetAmerican Chemical Society
PublisherData powered by TypesetAmerican Chemical Society (ACS)
Open AccessNo