The potential of higher frequency ultrasonic guided wave mode cluster (HOMC) waves to be used for remote inspection of notch defects in plate-like structures is investigated, at room and elevated temperatures. Quantitative studies of HOMC interaction with notch defects ranging from 5% to 50% of plate thickness are performed using 2D finite element simulations, and are validated by controlled experiments performed, firstly at room temperature. Analysis using reciprocity-based relations is used to uncover for the first time, how the constituent modes of HOMC play a vital role in their scattering processes. Further experiments are used to show that the results are stable up to 300 ̊C, thereby demonstrating the feasibility of short range higher-resolution remote inspection of notch defects using non-dispersive higher frequency mode clusters in industrial conditions. © 2021