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Redox polymerization of acrylamide initiated by the system V(III)(acac)3 hydroxylamine in dimethyl formamide
Venkatanarayana Mahadevan
Published in
Volume: 17
Issue: 11
Pages: 1185 - 1187
Kinetics of oxidation of Tris-acetylacetonato V(III) by hydroxylamine in DMF and the polymerization of acrylamide have been investigated in the temperature range 20-30°C. The oxidation is a second order process with polymerization being initiated and terminated by the amino radicals. Rate and thermodynamic data have been evaluated and their significance discussed. © 1981.
About the journal
JournalEuropean Polymer Journal
Open AccessNo