Rate constants for the reaction of phosphate radical with some aromatic and aliphatic amines have been determined by the flash photolysis technique. The products formed under conditions of continuous irradiation have been identified. In the case of an aromatic amine the major product is the azo compound while in the case of an aliphatic amine a carbonyl compound is formed. © 1986 Indian Academy of Sciences.

P. Subramanian

Jayaraman Rajaram

Joseph C. Kuriacose

IIT Madras is a public technical and research university located in Chennai, Tamil Nadu. Founded in 1959, it is recognised as an Institute of National Importance.

IIT Madras has been ranked as the top engineering institute in India for four years in a row by the National Institutional Ranking Framework of the MHRD

It currently offers undergraduate, postgraduate and research degrees across 16 disciplines in Engineering, Sciences, Humanities and Management. About 596 faculty belonging to science and engineering departments and centres of the Institute are engaged in teaching, research and industrial consultancy.

IIT Madras

Reaction of the phosphate radical with amines — A flash photolysis study

Proceedings of the Indian Academy of Sciences - Chemical Sciences

Carbonate radicals react with aliphatic amines by a dual mechanism, viz. (i) hydrogen abstraction and (ii) electron transfer. The former is more probable with primary amines. Tertiary amines react via electron transfer. Both mechanisms may operate in secondary amines. Cyclic tertiary amines react with different rates and their relative reactivities are explained on the basis of the concept of Hoffmann's 'through bond' interaction. © 1985.

Tetrahedron

Reactions of the carbonate radical with aliphatic amines

Journal of the American Chemical Society

Complexation and oxidation of glycine and related compounds by silver(II)

Substituent effect on the rate constants for the reactions between benzenethiyl radicals and stable free radicals estimated by flash photolysis

Russian Chemical Reviews

Inorganic Radical-ions and Their Organic Reactions

The Journal of Physical Chemistry

Phosphate radicals. Spectra, acid-base equilibriums, and reactions with inorganic compounds

Reaction of the phosphate radical with amines - A flash photolysis study

Journal	Data powered by TypesetProceedings of the Indian Academy of Sciences - Chemical Sciences
Publisher	Data powered by TypesetSpringer India
ISSN	03700089
Open Access	No