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Reaction of the carbonate radical with substituted anilines
T. P. Elango, S. Vancheesan, Joseph C. Kuriacose
Published in Springer India
Volume: 93
Issue: 1
Pages: 47 - 52
Rate constants for the reaction of carbonate radical with aniline and some parasubstituted anilines have been determined by the flash photolysis technique. Using σ+ para values the rate constants at pH 8.5 correlate very well with the Hammett equation yielding ρ= - 1. The carbonate radical oxidises aniline giving the anilino radical. The products so formed have been identified through studies under conditions of continuous irradiation. © 1984 Indian Academy of Sciences.
About the journal
JournalData powered by TypesetProceedings of the Indian Academy of Sciences - Chemical Sciences
PublisherData powered by TypesetSpringer India
Open AccessNo