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Palladium catalyzed aryl(alkyl)thiolation of unactivated arenes
Perumal Saravanan,
Published in
2014
PMID: 24437617
Volume: 16
   
Issue: 3
Pages: 848 - 851
Abstract
A general palladium-catalyzed aryl(alkyl)thiolation of various substituted unactivated arenes is accomplished for the synthesis of diverse unsymmetrical diaryl(alkyl) sulfides in good yield employing electrophilic sulfur reagent 6 derived from succinimide. The developed strategy was coupled with intramolecular arylation of a C-H bond to afford dibenzothiphene derivatives, an important moiety in material science as organic semiconductors. © 2014 American Chemical Society.
About the journal
JournalOrganic Letters
ISSN15237060
Open AccessNo
Concepts (12)
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    Dyes, reagents, indicators, markers and buffers
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    Palladium
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    Succinimide derivative
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    Article
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    Catalysis
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    Chemical structure
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    Chemistry
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    Hydrogen bond
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    Hydrogen bonding
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    Indicators and reagents
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    Molecular structure
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    Succinimides